Photovoltaic (PV) systems convert sunlight directly into electricity, while thermal systems produce thermal energy for residential heating systems such as hot water or space heaters. The differences also come down to how they capture energy from sunlight.
Purchase a roof-mounting kit (assuming you don't want to ground-mount your solar panels), then scope out your roof's support beams. Mark the location where you'll bolt the flashings. These flashings prevent leakage before you attach the mounts.
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